CY60003: Organic Photochemistry And Pericyclic Reactions
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| Course name | Organic Photochemistry And Pericyclic Reactions | ||||||||||||||||||||||||
| Offered by | Chemistry | ||||||||||||||||||||||||
| Credits | 3 | ||||||||||||||||||||||||
| L-T-P | 3-0-0 | ||||||||||||||||||||||||
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| Semester | Autumn | ||||||||||||||||||||||||
Syllabus
Syllabus mentioned in ERP
Prerequisite : NilPhotochemistry: Principles of photochemical reactions; Excited states and their properties; experimental set up for photochemical reactions; Several useful photochemical reactions and their applications in organic synthesis (isomerization, Patterno-Buchi reaction, Norrish type I and II reaction, Photoreduction, Rearrangements: di-Ï-methane, oxa di-Ï- and aza di-Ï-methane rearrangements, Photocycloaddition, Photochemical aromatic substitution reaction, Reactions with singlet oxygen, Photochemical methods for protection and deprotection). Photochemistry of biological systems (photosensitized reactions of DNA/RNA, DNA damage and repair). Pericyclic reactions: Conservation of molecular orbital symmetry, Symmetry properties of molecular orbitals, Transition state aromaticity, Aromaticity and anti aromaticity (Huckel and Mobius ring), Correlation diagrams and FMO method, Allowed and forbidden reactions, Electrocyclic reactions, Cycloaddition reactions ( 2 2; 4 2; 6 4; 3 2; 4 3 and related reactions, Cheleotropic addition and elimination), Sigmatropic rearrangement, Group transfer reactions (ene reactions).Books: Advanced Organic Chemistry: Structure and Mechanisms (Part A). By Frances A Carey and Richard J Sundberg. Springer; CRC Handbook of Photochemistry and Photobiology. Eds by. William M. Horspool and Pill-Soon Song, CRC Press; Organic Photochemistry (Vol 4) by Albert Padwa (Ed.). Mercel Dekker. Pericyclic reactions by Ian Fleming. Oxford University Press. Cycloaddition reactions in organic synthesis by W. Carruthers. Pergamon.
Concepts taught in class
Student Opinion
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Classroom resources
Additional Resources
Time Table
| Day | 8:00-8:55 am | 9:00-9:55 am | 10:00-10:55 am | 11:00-11:55 am | 12:00-12:55 pm | 2:00-2:55 pm | 3:00-3:55 pm | 4:00-4:55 pm | 5:00-5:55 pm | |
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| Monday | NC344 | |||||||||
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| Wednesday | NC344 | NC344 | ||||||||
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